I’ve always been quite partial to Star Wars: Bounty Hunter on the PS2. It’s not perfect but there aren’t really any other Star Wars games like it and the concept is very cool.
Other than that Rogue Squadron 3 for the GC and Shadows of the Empire on the N64 are absolutely killer.
Oh man, I forgot about Bounty Hunter. Yes, that game was awesome! Possibly the best thing to come out of the prequels, actually. Had a very OT feel.
It’s a shame we don’t get awesome single player games with great stories like that, Dark Forces, Jedi Knight, and even X Wing: Alliance very often anymore…