Duel of the Fates playing over a long shot of Anakin talking to a Jawa is one of the lower points of the entire PT.
It was a montage/road trip style scene and that shot of him talking to a jawa was a big wide shot that fit the music well.
Anakin was on a quest to save his mother. I think it’s usage was perfectly fine.
I could have swore Duel of The Fates played during the best duel in the PT…that seemed more fitting. Just my opinion though.