Starwars doesn't usually go on any list as it's a given, so will always be No.1
My favourite films tend to be those that made the biggest impact on me at the time, and no more modern films can ever achieve this impact again.
But for what its worth these films held me in awe when I first watched them, and still do today, in no particular order of preference, mostly sci-fi :)
Alien
Aliens
Bladerunner
The Thing '82
Invasion of the body snatchers '79
Repoman
Taxidriver
Day the Earth Stood Still '51
Terminator
Alien3 Directors Cut
Silence of the Lambs
Raiders of the lost Ark
Jaws
Dirty Harry
Predator
Ghostbusters