TIE: Mask of the Phantasm/Batman
Close 2nd. The Dark Knight.
TDK would be higher, if not for one to many repetitions of the "not the hero with think we need to deserve, but the hero we deserve to think we need" monologues.
To this day I've never seen the end of Batman and Robin. I walked out of the theater when Poison Ivy took out a talking plant in a pot or something that just was to damn lame. I flirted with the snack bar girl because my ride stayed in the theater, and actually scored a date, so it was worth it.