I think then its fair to assume that he will be a Captain of one of those early Star Destroyer ships we saw at the end of Ep2. Perhaps he is Captain of the ship that Obi-Wan is commanding the Clone Troopers that will eventually turn on him?
Perhaps this is how Tarkin learns of Obi-Wan, with reference to Ep4, otherwise perhaps we are meant to assume that Vader & Tarkin had a nice chat sometime between eps 3 & 4, when they were bored on the Death Star, perhaps dunking biscuits & listening to Mozart?
Not a lot else to do on a space station on a Sunday afternoon except reminisce on days gone is there?