Fantastic! I did a bit of research and DVD Video does support 24/96 PCM in Stereo. This site might help you: http://www.psaudio.com/ps/forum/forumdisplay.php/viewthread/12/
Which links to this site with a free program that supposedly will create the disk:
http://audioplex.sourceforge.net/
It is audio only, but at least should work on a dvd player so you can listen to it in full 24/96 if the player doesn't downconvert it.
There may be other programs that will do the video too. Just be careful that it doesn't downconvert the audio.
Hope this helps!
Mike