This sounds more like a computer project than a DVD project. Marvel put out a few DVDs of scans of YEARS worth of comics. I have the Spider-Man one that goes from the beginning in '62 all the way up to about 2006 or so. They're organized by decade, then by year, with each individual comic scanned in as a PDF file, ads and all. You can print them out or read them on the computer at your own pace, rather than having to have your finger on the pause button.

Might want to investigate doing it that way instead.