http://www.thewellers.com/startrek/enttmln.htm
I considered starting with Enterprise and doing a true chronological order, but I hear that that's the least loved of the saga and may put me off. Oh, and don't worry about me buying the whole thing at once. I'm not that stupid. I'll be buying these one season/movie at a time, so I can quit whenever. I'll be breaking the series up into subsets, and the episodes of each subset will be viewed in chronological order. The subsets are as follows:
The Original Series + The Animated Series + Movies 1-6
The Next Generation + Movies 7-10
Deep Space Nine
Voyager
Enterprise
So, essentially, I'm breaking it down by crew.