I also enjoy early episodes like the one with Peter Boyle (which also had Yappi) as a psychic insurance salesman and there was one where Mulder and Scully visited a trailer park of side-show freaks.
One later episode that I found amusing was the one with Gary Schandling, where they were "making a movie" about the X-Files.
"I have a confession Mulder, I'm in love with assistant director Skinner."
The show did trail off when Duchovny left, and things never good as good as they were even after he returned. I followed through to the end as best as I could. ******* in the final episode completely threw me.
Edited for spoilers

- Jay