Syndrome was a great villain BECAUSE he was so intense. He was the scorned nerd who came back for revenge; he is US, only pure evil. That's what makes him great... Plus his lines were great. "Oh-ho, this is just TOO GOOD!" where he says it like a hill-billy, or the "And when everyone is Super... NO ONE will be."
As for getting you copies of Disney films not in stores, sorry, but this forum is not for bootlegging.