TPM - Duel of the Fates
AoTC - Speeder Chase or the Republic march
RoTS - Anakin vs. Obi-Wan
Star Wars - the track that plays during the chasm shootout
ESB - Battle in the Snow, The Asteroid Field, or Departure of Boba Fett
ROTJ - Return of the Jedi, Into the Trap, or The Final Duel
The first 6 soundtracks are the only ones I actively listen to, so I don’t really have and favorite tracks from the anthologies (except the Vader in the hallway scene in RO) or the ST.