My complete list, with one or two from every album.
TPM - ‘Queen Amidala and the Naboo Palace’ (contains Anakin’s theme and the arrival on Coruscant music)
AOTC - ‘Love Pledge and the Arena’, which also contains Across the Stars.
ROTS - John Williams really outdid himself with this soundtrack. I don’t want to choose, but maybe ‘Enter Lord Vader’ and ‘The Immolation Scene’
STAR WARS - ‘Inner City’ and ‘The Desert and the Robot Auction’
TESB - ‘The Battle in the Snow’ and ‘Lando’s Palace’. The other greatest SW soundtrack.
ROTJ - ‘Luke and Leia’ and ‘The Emperor’
Rogue One - ‘Your Father Would Be Proud’ and ‘Guardians of the Whills suite’
Solo - ‘Train Heist’
TCW - ‘The Clones’ and ‘Burying the Dead’
Rebels - ‘It’s Over Now’ and a handful of the unreleased s4 music.
TM - ‘The Mandalorian’ and ‘The Baby’
TFA - ‘Rey’s Theme’
TLJ - ‘The Rebellion is Reborn’ and ‘Peace and Purpose’
TROS - ‘The Rise of Skywalker’ and ‘A New Home’