Phantom Menace a Tie between Anakin’s theme and the Duel of the Fates.
Attack of the Clones Across the Stars
Revenge of the Sith Battle of the Heroes, reprise of Throne room and end titles
Star Wars Chasm Crossfire, and Binary Sunset and Throne Room and End titles.
Empire Han and Leia’s Theme, the battle in the snow, Yoda’s theme, the asteroid field theme.
ROTJ The Return of the Jedi, Luke and Leia, the chorus when Luke and Vader duel.
Force Awakens Jedi Steps and Binary Sunset, Scherzo for X-wings.

Honestly the scores for star wars 1977 and empire strikes back 1980 are two of the best ever recorded for a film. There really are no bad songs or themes. I played the albums back to back so many times on vinyl.

I also probably played my arista records set the anthology a hundred times.