As for AC3, I tried comparing a clip of video with AC3 and then wav and the only difference I noticed was that the AC3 audio was slightly quieter but nothing significant.
The XviD file has now been created and I muxed the AC3 with it but oddly my media player crashes when you try to skip to any part of the video, so I re-encoded the audio as 256kbps mp3 using VirtualDub and there's zero problems with skipping to any part of the video. Plus there's good news for W95/W98 users, the final file came out at 4.02gb so I re-compressed the end credits slightly smaller, the full resulting file is now 3.99gb and plays fine on my Win98 PC. Now to do the subtitles...