Only going by official releases.

VHS:

mid-1980’s CBS/FOX VHS releases- One set and one sealed copy of ANH

1990 CBS/FOX Trilogy set- two sets including one sealed

1992 Trilogy set- My personal favorite of the sets. I have a few of these including one sealed. Also have the letterboxed set

1995 Faces set- The first SW set I owned. Have three opened and one sealed and also have the WS set.

1997 SE- The second set I owned. Have two FS sets including one sealed and also have the WS set.

TPM- Have two FS copies and three WS sets including one sealed.

ATOC- Two copies

Droids- One copy

DVD:

TPM- Two copies, one WS the other FS

AOTC- Two copies, one WS the other FS

ROTS- Two copies, one WS the other FS

2004 Trilogy set: Two sets, one WS the other FS

2006 DVDs: Two copies, one WS the other FS. WS DVDs came in a Best Buy exclusive tin case.

TFA- One copy

TLJ- One copy

R1- One copy