The Casino Royale PSP disc based on a clip of the credits I’ve seen on Youtube looks cropped to 16:9 rather than Open Matte:

https://m.youtube.com/watch?v=8KGlX1sITKY

Also, I was initially mistaken regarding the cap I made from ITV in regards to it been Open Matte, it is again, cropped to 16:9 like the PSP disc. I’m not sure if this is the case re other foreign broadcasts that were supposed OM, if so, it looks like only the Full Screen Dvd maybe Open Matte (I haven’t seen that myself to confirm).

Quantum of Solace on the other hand, again from ITV, is definitely Open Matte, although the latest showings of both this and CR have been theatrical 2.35:1.

Skyfall, both the initial Sky (which I capped) and ITV showings were definitely Open Matte as well but ITV again has lately updated to show only the theatrical 2.35:1 (since around the time of the Spectre ITV premiere)