Things being as they are, the best way to have handled this in RotS would be to have Leia born first, Padme hold her for a while, make eye contact, name her, and kiss her. Then she would go into a new set of contractions as the unexpected Luke arrives. She'd name him, then say "There's good in him; I know there is still," and die before getting to hold or look at Luke. This is what I think we were all expecting to happen; of course, that's probably why it didn't.
Things being as they are, the best way to have handled this in RotS would be to have Leia born first, Padme hold her for a while, make eye contact, name her, and kiss her. Then she would go into a new set of contractions as the unexpected Luke arrives. She'd name him, then say "There's good in him; I know there is still," and die before getting to hold or look at Luke. This is what I think we were all expecting to happen; of course, that's probably why it didn't.